Deoxygenation

Deoxygenation is a chemical reaction involving the removal of molecular oxygen (O2) from a reaction mixture or solvent, or the removal of oxygen atoms from a molecule.

Classic representatives of deoxygenation are:

A chemical reagent for the deoxygenation of many sulfur and nitrogen oxo compounds is the trifluoroacetic anhydride / sodium iodide combination [1] for example in the deoxygenation of the sulfoxide diphenylsulfoxide to the sulfide diphenylsulfide:

Sulfoxide deoxygenation

The reaction mechanism is based on activation of the sulfoxide by a trifluoroacetyl group and oxidation of iodine. Iodine is formed quantitatively in this reaction and therefore the reagent is used for the analytical detection of many oxo compounds.

TFAA NaI deoxygenation mechanism

See also

References

  1. ^ Trifluoroacetic anhydride-sodium iodide reagent. Nature and applications Arkivoc 2007 (JE-2136MR) Zbigniew H. Kudzin, Marcin H. Kudzin, Józef Drabowicz, and Andrzej Kotyński Link

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Look at other dictionaries:

  • Deoxygenation — De*ox y*gen*a tion, n. (Chem.) The act or operation of depriving of oxygen. [1913 Webster] …   The Collaborative International Dictionary of English

  • deoxygenation — deguonies šalinimas statusas T sritis ekologija ir aplinkotyra apibrėžtis Deguonies kiekio mažinimas, kai nuotekų valymą atlieka mikroorganizmai, kurių gyvybinei veiklai nereikia laisvojo deguonies. atitikmenys: angl. deoxygenation; oxygen… …   Ekologijos terminų aiškinamasis žodynas

  • deoxygenation — deoxygenate ► VERB ▪ remove oxygen from. DERIVATIVES deoxygenation noun …   English terms dictionary

  • deoxygenation — noun see deoxygenate …   New Collegiate Dictionary

  • deoxygenation — See deoxygenate. * * * …   Universalium

  • deoxygenation — noun The removal of oxygen atoms or molecules from a material …   Wiktionary

  • deoxygenation — de·ox·y·gen·a·tion (de ok″sĭ jən aґshən) the act of depriving of oxygen …   Medical dictionary

  • deoxygenation — n. removal of oxygen, elimination of oxygen …   English contemporary dictionary

  • deoxygenation — de·oxygenation …   English syllables

  • deoxygenation — noun see deoxygenate …   Useful english dictionary


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