Dry ice, sometimes referred to as "Cardice" or as "card ice", is the solid form of carbon dioxide. It is used primarily as a cooling agent. Its advantages include lower temperature than that of water ice and not leaving any residue (other than incidental frost from moisture in the atmosphere). It is useful for preserving frozen foods, ice cream, etc., where mechanical cooling is unavailable.
The extreme cold makes the solid dangerous to handle without protection due to burns caused by freezing (frostbite). While generally nontoxic, the outgassing from it can cause suffocation due to displacement of oxygen in confined locations.
At temperatures below −56.4 °C (−69.5 °F) and pressures below 5.13 atm (the triple point), CO2 changes from a solid to a gas with no intervening liquid form, through a process called sublimation. The opposite process is called deposition, where CO2 changes from the gas to solid phase (dry ice). At atmospheric pressure, sublimation/deposition occurs at −78.5 °C (−109.3 °F).
The density of dry ice varies, but usually ranges between about 1.4 and 1.6 g/cm3 (87–100 lb/ft3). The low temperature and direct sublimation to a gas makes dry ice an effective coolant, since it is colder than water ice and leaves no residue as it changes state. Its enthalpy of sublimation is 571 kJ/kg (25.2 kJ/mol).
It is generally accepted that dry ice was first observed in 1834 by French chemist Charles Thilorier, who published the first account of the substance. In his experiments, he noted that when opening the lid of a large cylinder containing liquid carbon dioxide, most of the liquid CO2 quickly evaporated. This left only solid dry ice in the container. In 1924, Thomas B. Slate applied for a US patent to sell dry ice commercially. Subsequently, he became the first to make dry ice successful as an industry. In 1925, this solid form of CO2 was trademarked by the DryIce Corporation of America as "Dry ice", thus leading to its common name. That same year the DryIce Co. sold the substance commercially for the first time; marketing it for refrigerating purposes.
Dry ice is easily manufactured. First, gases with a high concentration of carbon dioxide are produced. Such gases can be a byproduct of another process, such as producing ammonia from nitrogen and natural gas, or large-scale fermentation. Second, the carbon dioxide-rich gas is pressurized and refrigerated until it liquifies. Next, the pressure is reduced. When this occurs some liquid carbon dioxide vaporizes, causing a rapid lowering of temperature of the remaining liquid. As a result, the extreme cold causes the liquid to solidify into a snow-like consistency. Finally, the snow-like solid carbon dioxide is compressed into either small pellets or larger blocks of dry ice.
Dry ice is typically produced in two standard forms: blocks and cylindrical pellets. A standard block weighing approximately 30 kg is most common. These are commonly used in shipping, because they sublimate relative slowly due to a low ratio of surface area to volume. Pellets are around 1 cm (0.4 in) in diameter and can be bagged easily. This form is suited to small scale use, for example at grocery stores and laboratories.
Dry ice can be used to arrest and prevent insect activity in closed containers of grains and grain products, as it displaces oxygen, but does not alter the taste or quality of such foods. For the same reason, it can prevent or retard food oils and fats from becoming rancid.
When dry ice is placed in water sublimation is accelerated, and low-sinking, dense clouds of smoke-like fog are created. This is used in fog machines, at theaters, discothèques, haunted house attractions, and nightclubs for dramatic effects. Unlike most artificial fog machines, in which fog rises like smoke, fog from dry ice hovers above the ground. Dry ice is useful in theater productions that require dense fog effects.
It is occasionally used to freeze and remove warts. However, liquid nitrogen performs better in this role, since it is colder so requires less time to act and less pressure. However, dry ice has the advantage of having fewer problems with storage, since it can be generated from compressed carbon dioxide gas as needed.
Plumbers use equipment that forces pressurised liquid CO2 into a jacket around a pipe; the dry ice formed causes the water to freeze, forming an ice plug, allowing them to perform repairs without turning off the water mains. This technique can be used on pipes up to 4 inches (100 mm) in diameter.
One of the largest mechanical uses of dry ice is blast cleaning. Dry ice pellets are shot out of a nozzle with compressed air, combining the power of the speed of the pellets with the action of the sublimation. This can remove residues from industrial equipment. Examples of materials being removed include ink, glue, oil, paint, mold and rubber. Dry ice blasting can replace sandblasting, steam blasting, water blasting or solvent blasting. The primary environmental residue of dry ice blasting is the sublimed CO2, thus making it a useful technique where residues from other blasting techniques are undesirable.[dead link] Recently, blast cleaning has been introduced into the industry of removing smoke damage from structures after fires.
Dry ice is also useful for the de-gassing of flammable vapours from storage tanks — the sublimation of dry ice pellets inside an emptied and vented tank causes an outrush of CO2 that carries with it the flammable vapours.
The removal and fitting of cylinder liners in large marine engines requires the use of dry ice to chill and thus shrink the liner so that it freely slides within the block. When warmed in place the resulting interference fit prevents motion. Similar procedures may be used in fabricating mechanical assemblies with a high resultant strength, replacing the need for pins, keys or welds.
It is also useful as a cutting fluid.
The process of altering cloud precipitation can be done with the use of dry ice. It was widely used in experiments in the US in the 1950s and early 60s before being replaced by silver iodide. Dry ice has the advantage of being relatively cheap and completely non-toxic. Its main drawback is the need to be delivered directly into the supercooled region of clouds being seeded.
Dry ice bombs
Dry ice is an ingredient in dry ice bombs. A dry ice bomb is a bomb-like device using dry ice and water-filled container, such as a plastic bottle. As the dry ice sublimates, pressure increases, usually causing the bottle to explode.
California law defines "destructive device" as a type of weapon, including "any sealed device containing dry ice (CO2) or other chemically-reactive substances assembled for the purpose of causing an explosion by a chemical reaction." However, dry ice bombs operate not via chemical reaction but via a phase change. The approximate volume of carbon dioxide gas produced by sublimating a known mass of dry ice can be calculated using the Ideal gas law.
Prolonged exposure to dry ice can cause severe skin damage through frostbites, and the fog produced may also hinder attempts to withdraw from contact in a safe manner. Because it sublimates into large quantities of carbon dioxide gas, which could displace oxygen-containing air and pose a danger of asphyxiation, dry ice should only be exposed to open air in a well-ventilated environment. For this reason, dry ice is assigned the S-phrase in the context of laboratory safety. Industrial dry ice may contain contaminants that make it unsafe for direct contact with foodstuffs.
Although dry ice is not classified as a dangerous substance by the European Union, or as a hazardous material by the DOT for ground transportation, when shipped by air or water, it is regulated as a dangerous good and IATA packing instruction 904 (IATA PI 904) requires that it be labeled specially, including a diamond-shaped black-and white label, UN 1845. Also, arrangements must be in place to ensure adequate ventilation so that pressure build-up does not rupture the packaging. The Federal Aviation Administration in the US allows airline passengers to carry up to 2 kg of dry ice in carry-on baggage and 2.3 kg in checked baggage, when used to refrigerate perishables.
Occurrence on Mars
Following the Mars flyby of the Mariner 4 spacecraft in 1966, scientists concluded that Mars' polar caps consist entirely of dry ice. However, findings made in 2003 by researchers at the California Institute of Technology have shown that Mars' polar caps are almost completely made of water ice, and that dry ice only forms a thin surface layer that thickens and thins seasonally. A phenomenon named dry ice storms was proposed to occur over the polar regions of Mars. They are comparable to Earth's thunderstorms, with crystalline CO2 taking the place of water in the clouds.
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