- Salt bridge
A salt bridge, in
chemistry, is a laboratory device used to connect the oxidationand reduction half-cells of a galvanic cell(voltaic cell), a type of electrochemical cell. Salt bridge usually comes in two types: glass tube and filter paper.
Glass tube bridges
One type of salt bridges consists of U-shaped glass tubes filled with a relatively inert
electrolyte, usually potassium chlorideor sodium chloride. Agaris often used for gelification.
The conductivity of the glass tube bridges depends mostly on the concentration of the electrolyte solution. An increase in concentration below saturation increases conductivity. Beyond-saturation electrolyte content and narrow tube diameter may both lower conductivity.
Filter paper bridges
The other type of salt bridges consists of a filter paper, also soaked with a relatively inert electrolyte, usually potassium chloride or sodium chloride because they are chemically
inert. No gelification agent is required as the filter paper provides a solid medium for conduction. Conductivityof this kind of salt bridges depends on a number of factors: the concentrationof the electrolyte solution, the texture of the filter paper and the absorbing ability of the filter paper. Generally smoother texture and higher absorbancy equates to higher conductivity.
A porous disk or other porous barrier between the two half-cells may be used instead of a salt bridge; however, they basically serve the same purpose.
As electrons leave one half of a galvanic cell and flow to the other, a difference in charge is established. If no salt bridge was used, this charge difference would prevent further flow of electrons. A salt bridge allows the flow of
ionsto maintain a balance in charge between the oxidation and reduction vessels while keeping the contents of each separate. With the charge difference balanced, electrons can flow once again, and the reduction and oxidation reactions can proceed. In general, keeping the two cells separate is preferable from the point of view of eliminating variables from an experiment. When no direct contact between electrolytes is allowed, there is no need to make allowance for possible interactions between ionic species.
The technique more specifically allows freedom in the choice of ions in
solution. For instance, a mixtureof two different cations in solution might result in the preferential reduction of the wrong one, for the purposes of the experiment. With a salt bridge, the desired cation is isolated in one vessel while the cation in the other vessel may be chosen to make the experiment easier, e.g. using a more soluble, or more stable salt of the anionic species.
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